International Union of Pure and Applied Chemistry
Polymer Division
Subcommittee on Polymer Terminology
A Brief Guide to Polymer Nomenclature
Version 1.1 (2012)
1) Introduction
The universal adoption of an agreed nomenclature has never been more
important for the description of chemical structures in publishing and on-line
searching. The International Union of Pure and Applied Chemistry (IUPAC)
1a,b
and Chemical Abstracts Service (CAS)
2
make similar recommendations.
The main points are shown here with hyperlinks to original documents.
Further details can be found in the IUPAC Purple Book.
3
2) Basic Concepts
The terms polymer and macromolecule do not mean the same thing. A polymer
is a substance composed of macromolecules. The latter usually have a range of
molar masses (unit g mol
-1
), the distributions of which are indicated by
dispersity (Đ). It is defined as the ratio of the mass-average molar mass (M
m
) to
the number-average molar mass (M
n
) i.e. Đ = M
m
/M
n
.
4
Symbols for physical
quantities or variables are in italic font but those representing units or labels are
in roman font.
Polymer nomenclature usually applies to idealised representations; minor
structural irregularities are ignored. A polymer can be named in one of two
ways. Source-based nomenclature can be used when the monomer can be
identified. Alternatively, more explicit structure-based nomenclature can be used
when the polymer structure is proven. Where there is no confusion, some
traditional names are also acceptable.
Whatever method is used, all polymer names have the prefix poly, followed by
enclosing marks around the rest of the name. The marks are used in the order:
{[( )]}. Locants indicate the position of structural features, e.g., poly(4-
chlorostyrene). If a source-based name is one word and has no locants, then the
enclosing marks are not essential, but they should be used when there might be
confusion, e.g., poly(chlorostyrene) is a polymer whereas polychlorostyrene
might be a small, multi-substituted molecule. End-groups are described with
α- and ω-, e.g., α-chloro-ω-hydroxy-polystyrene.
3
3) Source-Based Nomenclature
5
3.1 Homopolymers
A homopolymer is named using the name of the real or assumed monomer (the
‘source’) from which it is derived, e.g., poly(methyl methacrylate). Monomers
can be named using IUPAC recommendations, or well-established traditional
names. Should ambiguity arise, class names can be added.
6
For example, the
source-based name poly(vinyloxirane) could correspond to either of the
structures shown below. To clarify,
the polymer is named using the
polymer class name followed by
a colon and the name of the
monomer, i.e., class name:monomer name. Thus on the left and right,
respectively, are polyalkylene:vinyloxirane and polyether:vinyloxirane.
3.2 Copolymers
7
The structure of a copolymer can be described using the most appropriate of the
connectives shown in Table 1. These are written in italic font.
3.3 Non-linear polymers
5
Non-linear polymers and copolymers, and polymer assemblies are named using
the italicized qualifiers in Table 2. The qualifier, such as branch, is used as a
prefix (P) when naming a (co)polymer, or as a connective (C), e.g., comb,
between two polymer names.
Table 1 – Qualifiers for copolymers.
7
Copolymer Qualifier Example
uns
ecified co
C
ol
st
rene-co-iso
rene
statistical stat (C) poly[isoprene-stat-(methyl methacrylate)]
random ran (C) poly[(methyl methacrylate)-ran-(butyl acrylate)]
alternatin
alt
C
ol
[st
rene-alt-
maleic
anh
dride
]
periodic per (C) poly[styrene-per-isoprene-per-(4-vinylpyridine)]
block block
C
ol
buta-1,3-diene
-block-
ol
ethene-co-
ro
ene
raft
a
ra
t
C
ol
st
rene-
ra
t-
ol
eth
lene
oxide
a
The first name is that of the main chain.
Table 2 – Qualifiers for non-linear (co)polymers and polymer assemblies.
5
(Co)polymer Qualifier Example
blend blend (C)
poly(3-hexylthiophene)-blend-
polystyrene
comb comb
C
ol
st
rene-comb-
ol
iso
rene
complex compl (C)
poly(2,3-dihydrothieno[3,4-
b][1,4]dioxine)-compl-
ol
vin
lbenzenesulfonic
acid
a
cyclic cyclo (P) cyclo-polystyrene-graft-polyethylene
branch branch (P)
branch-poly[(1,4-divinylbenzene)-
stat-styrene]
network net (C or P) net-poly(phenol-co-formaldehyde)
interpenetrating network ipn (C)
(net-polystyrene)-ipn-[net-
poly(methyl acrylate)]
semi-interpenetrating
network
sipn (C) (net-polystyrene)-sipn-polyisoprene
star star (P) star-polyisoprene
a
In accordance with IUPAC organic nomenclature, square brackets enclose locants that
refer to the numbering of the components of the fused ring.
4) Structure-Based Nomenclature
4.1 Regular single-strand organic polymers
8
In place of the monomer name used in source-based nomenclature, structure-
based nomenclature uses that of the preferred constitutional repeating unit
(CRU). It can be determined as follows: (i) a large enough part of the polymer
chain is drawn to show the structural repetition, e.g.,
CH
Br
CH
2
OCH
Br
CH
2
OCH
Br
CH
2
O
(ii) the smallest repeating portion is a CRU, so all such possibilities are
identified. In this case:
OCH
Br
CH
2
CH
2
OCH
Br
OCH
2
CH
Br
OCH
Br
CH
2
CH OCH
2
Br
CH
Br
CH
2
O
(iii) the next step is to identify the subunits that make up each of these
structures, i.e., the largest divalent groups that can be named using IUPAC
nomenclature of organic compounds such as the examples that are listed in
Table 3; (iv) using the shortest path from the most senior subunit to the next
senior, the correct order of the subunits is determined using Figure 1; (v) the
preferred CRU is chosen as that with the lowest possible locant(s) for
substituents.
In the above example, the oxy subunits in the CRUs are heteroatom chains.
From Figure 1, oxy subunits are senior to the acyclic carbon chain subunits, the
largest of which are bromo-substituted -CH
2
-CH
2
- subunits. 1-Bromoethane-1,2-
diyl is chosen in preference to 2-bromoethane-1,2-diyl as the former has a lower
locant for the bromo-substituent. The preferred CRU is therefore oxy(1-
bromoethane-1,2-diyl) and the polymer is thus named poly[oxy(1-bromoethane-
1,2-diyl)]. Please note the enclosing marks around the subunit carrying the
substituent.
Polymers that are not made up of regular repetitions of a single CRU are called
irregular polymers. For these, each constitutional unit (CU) is separated by
a slash, e.g., poly(but-1-ene-1,4-diyl/1-vinylethane-1,2-diyl).
9
R. C. Hiorns (France),* R. J. Boucher (UK), R. Duhlev (UK), K.-H. Hellwich (Germany), P. Hodge (UK), A. D. Jenkins (UK), R. G. Jones (UK),
J. Kahovec (Czech Republic), G. Moad (Australia), C. K. Ober (USA), D. W. Smith (USA), R. F. T. Stepto (UK), J.-P. Vairon (France), and J. Vohlídal
(Czech Republic). *E-mail:
[email protected]; Sponsoring body: IUPAC Polymer Division, Subcommittee on Polymer Terminology. 1
Freely available on: (a) http://www.iupac.org/publications/pac/;
(b) http://www.chem.qmul.ac.uk/iupac/
2
http://www.cas.org/.
3
IUPAC. The “Purple Book”, RSC Publishing, (2008).
4
IUPAC. Pure Appl. Chem. 81, 351—352 (2009).
5
IUPAC. Pure Appl. Chem. 69, 2511—2521 (1997).
6
IUPAC. Pure Appl. Chem. 73, 1511—1519 (2001).
7
IUPAC. Pure Appl. Chem. 57, 1427—1440 (1985).
8
IUPAC. Pure Appl. Chem. 74, 1921—1956 (2002).
9
IUPAC. Pure Appl. Chem. 66, 873—889 (1994).
CH CH
2
O
n
CH CH
2
n
O
CH
CH
2